What I am seeing looks like trimmer pots, which have their value set during alignment at the factory.
Two possibilities:
1) A strange lubricant was injected in them at the factory.
2) A fixing paint was dabbed on them once the value was set at the factory.
#1 is unlikely, #2 is very likely. It is very common that once a critical value is set, a dab of paint or other locking agent is applied to the pot. These appear to be trimmer pots.
Now, your second question- You
call it "goo" which is interesting. Usually, fixing paint is hard, like
nail polish. I can't help wonder if the paint used reacted with the lubricant in the control to change it's composition. If this is the case, all bets are off as we do not know how conductive or corrosive the "new" goo is. So, it could affect operation.
Basically, a trimmer pot is a thin layer of carbon deposited on a
wafer with a variable
taper made of metal. In all cases, there is also a light grease like lubricant to inhibit oxidization as well as smooth out the feel. Strange orange goo is not a standard part of the assembly